Research Papers: Other (Seals, Manufacturing)

Effects of Particle Loading and Particle Size on Tribological Properties of Biochar Particulate Reinforced Polymer Composites

[+] Author and Article Information
S. Richard

Department of Mechanical Engineering,
Dr. Sivanthi Aditanar College of Engineering,
Tiruchendur 628215, Tamil Nadu, India
e-mail: iamrichi@yahoo.com

J. Selwin Rajadurai

Department of Mechanical Engineering,
Government College of Engineering,
Tirunelveli 627007, Tamil Nadu, India
e-mail: j_selwinrajadurai@yahoo.co.in

V. Manikandan

Department of Mechanical Engineering,
Kalasalingam University,
Krishnankoil 626190, Tamil Nadu, India
e-mail: vaimanikandan@yahoo.com

Contributed by the Tribology Division of ASME for publication in the JOURNAL OF TRIBOLOGY. Manuscript received November 6, 2015; final manuscript received February 2, 2016; published online July 20, 2016. Assoc. Editor: Mircea Teodorescu.

J. Tribol 139(1), 012202 (Jul 20, 2016) (10 pages) Paper No: TRIB-15-1397; doi: 10.1115/1.4033131 History: Received November 06, 2015; Revised February 02, 2016

In this research work, pulverized biochar obtained by the pyrolysis of rice husk is used as particulate reinforcement in unsaturated polyester matrix. The effects of the particle loading and particle size on tribological properties of the particulate composites were investigated. The average size of biochar particles obtained through pulverizing using ball-mill varied from 510 nm to 45 nm while milling for a duration ranging from 6 hrs to 30 hrs. The particle loading in the composite was varied from 0.5 wt.% to 2.5 wt.%. It was observed that the particle size and particle content played a vital role in the tribological properties of the composites. The specific wear rate of the specimen having particle loading of 2.5 wt.% with 45 nm particle size exhibited a decrease of 56.36% upon comparing with the specific wear rate of cured pure resin. The coefficient of friction of the same sample decreased by 6.42% when compared to that of a cured pure resin. The biochar particles were subjected to X-ray diffraction (XRD), Fourier transform infrared (FT-IR), and atomic force microscope analysis for characterization. Morphological studies were performed on the worn surfaces by scanning electron microscope (SEM) and optical microscopy.

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Velmurugan, R. , and Manikandan, V. , 2007, “ Mechanical Properties of Palmyra/Glass Fiber Hybrid Composites,” Compos. Part A, 38(10), pp. 2216–2226. [CrossRef]
Sreenivasan, V. S. , Ravindran, D. , Manikandan, V. , and Narayanasamy, R. , 2011, “ Mechanical Properties of Randomly Oriented Short Sansevieria Cylindrica Fibre/Polyester Composites,” Mater. Des., 32(4), pp. 2444–2455. [CrossRef]
Antunes, P. V. , Ramalho, A. , and Carrilho, E. V. P. , 2014, “ Mechanical and Wear Behaviours of Nano and Microfilled Polymeric Composite: Effect of Filler Fraction and Size,” Mater. Des., 61, pp. 50–60. [CrossRef]
Arumuga Prabu, V. , Uthayakumar, M. , Manikandan, V. , Rajini, N. , and Jeyaraj, P. , 2014, “ Influence of Redmud on the Mechanical, Damping and Chemical Resistance Properties of Banana/Polyester Hybrid Composites,” Mater. Des., 64, pp. 270–279. [CrossRef]
Beardmore, P. , 1986, “ Composite Structures for Automobiles,” Compos. Struct., 5(3), pp. 163–176. [CrossRef]
Feng, D. , Ya-Hong, X. U. , Ya-Ping, Z. , and Xiao-Su, Y. I. , 2005, “ Study on Morphology and Mechanical Properties of High Functional Epoxy Based Clay Nano Composites,” Chin. J. Aeronaut., 18(3), pp. 279–282. [CrossRef]
Chauhan, S. R. , and Thakur, S. , 2013, “ Effects of Particle Size, Particle Loading and Sliding Distance on the Friction and Wear Properties of Cenosphere Particulate Filled Vinylester Composites,” Mater. Des., 51, pp. 398–408. [CrossRef]
Matthews, F. L. , and Rawlings, R. D. , 2005, Composite Materials: Engineering and Science, 1st ed., Woodhead Publishing Ltd., Cambridge, UK, pp. 169–173, 310–311.
Nourbakhsh, A. , and Ashori, A. , 2010, “ Wood Plastic Composites From Agro-Waste Materials: Analysis of Mechanical Properties,” Bioresour. Technol., 101(7), pp. 2525–2528. [CrossRef] [PubMed]
Ashori, A. , and Nourbakhsh, A. , 2010, “ Bio-Based Composites From Waste Agricultural Residues,” Waste Manage., 30(4), pp. 680–684. [CrossRef]
Son, J. I. , Yang, H. S. , and Kim, H. J. , 2004, “ Physico-Mechanical Properties of Paper Sludge-Thermoplastic Polymer Composites,” J. Thermoplast. Compos. Mater., 17(6), pp. 509–522. [CrossRef]
Bhattacharya, S. K. , and Tummala, R. R. , 2001, “ Integral Passives for Next Generation of Electronic Packaging: Application of Epoxy/Ceramic Nanocomposites as Integral Capacitors,” Microelectron. J., 32(1), pp. 11–19. [CrossRef]
Naganuma, T. , and Kagawa, Y. , 2002, “ Effect of Particle Size on the Optically Transparent Nano Meter-Order Glass Particle-Dispersed Epoxy Matrix Composites,” Compos. Sci. Technol., 62(9), pp. 1187–1189. [CrossRef]
Rong, M. Z. , Zhang, M. Q. , Liu, H. , Zeng, H. , Wetzel, B. , and Friedrich, K. , 2001, “ Microstructure and Tribological Behavior of Polymeric Nanocomposites,” Ind. Lubr. Tribol., 53(2), pp. 72–77. [CrossRef]
Li, F. , Hu, K.-A. , Li, J.-L. , and Zhao, B.-Y. , 2002, “ The Friction and Wear Characteristics of Nanometer ZnO Filled Polytetrafluoroethylene,” Wear, 249(10–11), pp. 877–882. [CrossRef]
Zhang, M. Q. , Rong, M. Z. , Yu, S. L. , Wetzel, B. , and Friedrich, K. , 2002, “ Improvement of Tribological Performance of Epoxy by the Addition of Irradiation Grafted Nano-Inorganic Particles,” Macromol. Mater. Eng., 287(2), pp. 111–115. [CrossRef]
Ng, C. B. , Schadler, L. S. , and Siegel, R. W. , 1999, “ Synthesis and Mechanical Properties of TiO2-Epoxy Nanocomposites,” Nanostruct. Mater., 12(1–4), pp. 507–510. [CrossRef]
Zhang, Q. X. , Yu, Z. Z. , Xie, X. L. , and Mai, Y. W. , 2004, “ Crystallization and Impact Energy of Polypropylene/CaCO3 Nanocomposites With Nonionic Modifier,” Polymer, 45(17), pp. 5985–5994. [CrossRef]
Wang, W. Z. , and Liu, T. X. , 2008, “ Mechanical Properties and Morphologies of Polypropylene Composites Synergistically Filled by Styrene–Butadiene Rubber and Silica Nanoparticles,” J. Appl. Polym. Sci., 109(3), pp. 1654–1660. [CrossRef]
Tjong, S. C. , and Bao, S. , 2007, “ Structure and Mechanical Behavior of Isotactic Polypropylene Composites Filled With Silver Nanoparticles,” E-Polymers, 7(1), pp. 1618–1634.
Liu, Y. Q. , and Kontopoulou, M. , 2006, “ The Structure and Physical Properties of Polypropylene and Thermoplastic Olefin Nanocomposites Containing Nanosilica,” Polymer, 47(22), pp. 7731–7739. [CrossRef]
Suresha, G. B. , Ravi Kumar, B. N. , Venkataramareddy, M. , and Jayaraju, T. , 2010, “ Role of Micro/Nano Fillers on Mechanical and Tribological Properties of Polyamide66/Polypropylene Composites,” Mater. Des., 31(4), pp. 1993–2000. [CrossRef]
Rong, M. Z. , Zhang, M. Q. , Zheng, Y. X. , Zeng, H. M. , Walter, R. , and Friedrich, K. , 2001, “ Structure–Property Relationships of Irradiation Grafted Nano-Inorgnic Particle Filled Polypropylene Composites,” Polymer, 42(1), pp. 167–83. [CrossRef]
Lin, J. C. , 2007, “ Compression and Wear Behavior of Composites Filled With Various Nanoparticles,” Compos. Part B, 38(1), pp. 79–85. [CrossRef]
Sun, T. , Fan, H. , Wang, Z. , Liu, X. , and Wu, Z. , 2015, “ Modified Nano Fe2O3-Epoxy Composite With Enhanced Mechanical Properties,” Mater. Des., 87, pp. 10–16.
Bahadur, S. , and Sunkara, C. , 2005, “ Effect of Transfer Film Structure, Composition and Bonding on the Tribological Behavior of Polyphenylene Sulfide Filled With Nano Particles of TiO2, ZnO, CuO and SiC,” Wear, 258(9), pp. 1411–1421. [CrossRef]
Li, C. , Zhong, Z. , Lin, Y. , and Klaus, F. , 2007, “ Tribological Properties of High Temperature Resistant Polymer Composites With Fine Particles,” Tribol. Int., 40(7), pp. 1170–1178. [CrossRef]
Kurahatti, R. V. , Surendranathan, A. O. , Srivastava, S. , Singh, N. , Ramesh Kumar, A. V. , and Suresha, B. , 2011, “ Role of Zirconia Filler on Friction and Dry Sliding Wear Behaviour of Bismaleimide Nanocomposites,” Mater. Des., 32(5), pp. 2644–2649. [CrossRef]
Tuck, C. , Perez, E. , Horvath, I. , Sheldon, R. , and Poliakoff, M. , 2012, “ Valorization of Biomass: Deriving More Value From Waste,” Science, 337(6095), pp. 695–699. [CrossRef] [PubMed]
Johar, N. , Ahmad, I. , and Dufresne, A. , 2012, “ Extraction, Preparation and Characterization of Cellulose Fibres and Nanocrystals From Rice Husk,” Ind. Crops Prod., 37(1), pp. 93–99. [CrossRef]
Turmanova, S. , Genieva, S. , and Vlaev, L. , 2012, “ Obtaining Some Polymer Composites Filled With Rice Husks Ash-A Review,” Int. J. Chem., 4(4), pp. 62–89. [CrossRef]
Satheesh Raja, R. , Manisekar, K. , and Manikandan, V. , 2014, “ Study on Mechanical Properties of Fly Ash Impregnated Glass Fiber Reinforced Polymer Composites Using Mixture Design Analysis,” Mater. Des., 55, pp. 499–508. [CrossRef]
Arumuga Prabu, V. , Manikandan, V. , and Uthayakumar, M. , 2012, “ Friction and Dry Sliding Wear Behavior of Red Mud Filled Banana Fibre Reinforced Unsaturated Polyester Composites Using Taguchi Approach,” Mater. Phys. Mech., 1, pp. 34–45.


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Fig. 5

One of the fabricated samples of Biochar reinforced composite

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Fig. 4

Variation of mean particle size with varying milling hours

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Fig. 3

Particle size distribution of biochar milled for 12 hrs

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Fig. 2

Biochar particle after ball milling

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Fig. 1

(a) Rice husk and (b) Biochar

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Fig. 7

SEM image of biochar particles after milling

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Fig. 8

Topography of the biochar particulate

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Fig. 10

XRD pattern of biochar particles

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Fig. 11

Void fraction of different composite specimen

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Fig. 12

Variation of specific wear rate with biochar wt.% in composite specimen

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Fig. 13

Variation of coefficient of friction with biochar wt.% in composite specimen

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Fig. 9

FT-IR spectroscopy of biochar particles

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Fig. 18

SEM pictures of the worn surfaces of biochar particulate (140 nm) reinforced composites with particle loading of 0.5 wt.% (a) and 2.5 wt.% (b)

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Fig. 19

SEM pictures of the worn surfaces of biochar particulate (45 nm) reinforced composites with particle loading of 0.5 wt.% (a) and 2.5 wt.% (b)

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Fig. 20

Optical micrographs of the worn surface of pure polyester resin

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Fig. 21

Optical micrographs of the worn surfaces of biochar particulate reinforced composite specimen A5 (a), B5 (b), C5 (c), D5 (d), and E5 (e)

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Fig. 14

SEM image of worn surface of clear polyester resin

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Fig. 15

SEM pictures of the worn surfaces of biochar particulate (510 nm) reinforced composites with particle loading of 0.5 wt.% (a) and 2.5 wt.% (b)

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Fig. 16

SEM pictures of the worn surfaces of biochar particulate (430 nm) reinforced composites with particle loading of 0.5 wt.% (a) and 2.5 wt.% (b)

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Fig. 17

SEM pictures of the worn surfaces of biochar particulate (230 nm) reinforced composites with particle loading of 0.5 wt.% (a) and 2.5 wt.% (b)



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