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Research Papers: Micro-Nano Tribology

Facile Synthesis of Uniform Calcite Microcubes and Their Enhanced Tribological Performance in Lithium-Based Commercial Grease

[+] Author and Article Information
Khalida Akhtar

National Centre of Excellence in Physical Chemistry,
University of Peshawar,
Peshawar 25120, Khyber Pakhtunkhwa, Pakistan
e-mail: khalidaakhtar@uop.edu.pk

Abid Hussain

National Centre of Excellence in Physical Chemistry,
University of Peshawar,
Peshawar 25120, Khyber Pakhtunkhwa, Pakistan
e-mail: abidturi@hotmail.com

Muhammad Gul

National Centre of Excellence in Physical Chemistry,
University of Peshawar,
Peshawar 25120, Khyber Pakhtunkhwa, Pakistan
e-mail: mg46asim@gmail.com

Hina Khalid

National Centre of Excellence in Physical Chemistry,
University of Peshawar,
Peshawar 25120, Khyber Pakhtunkhwa, Pakistan
e-mail: hinakhd@yahoo.com

Saniya Yousaf Zai

National Centre of Excellence in Physical Chemistry,
University of Peshawar,
Peshawar 25120, Khyber Pakhtunkhwa, Pakistan
e-mail: yousafzaaai2468@gmail.com

1Corresponding author.

Contributed by the Tribology Division of ASME for publication in the Journal of Tribology. Manuscript received October 1, 2018; final manuscript received January 24, 2019; published online March 11, 2019. Assoc. Editor: Min Zou.

J. Tribol 141(5), 052002 (Mar 11, 2019) (9 pages) Paper No: TRIB-18-1408; doi: 10.1115/1.4042677 History: Received October 01, 2018; Accepted January 25, 2019

This study describes a facile synthesis of calcium carbonate (CaCO3) monodispersed fine particles from an abundant indigenous and economical source (quicklime) and its enhanced tribological performance as a green additive in commercial lithium grease (CLG). The effects of various experimental parameters on particle morphology were thoroughly examined, and the conditions were optimized. The synthesized uniform particles were characterized by scanning electron microscopy, Fourier transform infrared spectroscopy, X-ray diffractometry, and thermogravimetric (TG) /differential thermal analysis (DTA), and their results confirmed the calcite structure of the synthesized particles. The friction and wear studies were carried out under the applied load of 0.863 N at an ambient temperature for 5 min. The tribological performance of various amounts (1–7%) of cubic-CaCO3 (CCC) particles in CLG showed that 5 wt. % of CCC was the optimum concentration as additive in the present case. For comparison purposes, a commercial CaCO3 powder was used and a decrease in the friction coefficient of CLG was observed to be 33.4% and 16.4% for 5 wt. % CCC and commercial CaCO3 additives, respectively. The significantly enhanced antiwear and antifriction performance of the optimum CCC-CLG in comparison with the blank and commercial CaCO3-additized CLG was quite encouraging, and extensive studies in a real machine-operating environment are in progress for evaluation of the CCC-CLG blend to be used as an economical, green, and high-performance lubricant in mechanical components.

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References

Kim, H.-J., Seo, K.-J., Kang, K. H., and Kim, D.-E., 2016, “Nano-Lubrication: A Review,” Int. J. Precision Eng. Manuf., 17, pp. 829–841. [CrossRef]
Dai, W., Kheireddin, B., Gao, H., and Liang, H., 2016, “Roles of Nanoparticles in Oil Lubrication,” Tribol. Int., 102, pp. 88–98. [CrossRef]
Zhou, J., Wu, Z., Zhang, Z., Liu, W., and Xue, Q., 2000, “Tribological Behavior and Lubricating Mechanism of Cu Nanoparticles in Oil,” Tribol. Lett., 8, pp. 213–218. [CrossRef]
Padgurskas, J., Rukuiza, R., Prosyčevas, I., and Kreivaitis, R., 2013, “Tribological Properties of Lubricant Additives of Fe, Cu and Co Nanoparticles,” Tribol. Int., 60, pp. 224–232. [CrossRef]
Xue, Q., Liu, W., and Zhang, Z., 1997, “Friction and Wear Properties of a Surface-Modified TiO2 Nanoparticle as an Additive in Liquid Paraffin,” Wear, 213, pp. 29–32. [CrossRef]
Luo, T., Wei, X., Zhao, H., Cai, G., and Zheng, X., 2014, “Tribology Properties of Al2O3/TiO2 Nanocomposites as Lubricant Additives,” Ceram. Int., 40, pp. 10103–10109. [CrossRef]
Chen, S., and Liu, W., 2001, “Characterization and Antiwear Ability of Non-Coated ZnS Nanoparticles and DDP-Coated ZnS Nanoparticles,” Mater. Res. Bull., 36, pp. 137–143. [CrossRef]
Hu, Z. S., Lai, R., Lou, F., Wang, L., Chen, Z., Chen, G., and Dong, J., 2002, “Preparation and Tribological Properties of Nanometer Magnesium Borate as Lubricating Oil Additive,” Wear, 252, pp. 370–374. [CrossRef]
Zhou, J., Wu, Z., Zhang, Z., Liu, W., and Dang, H., 2001, “Study on an Antiwear and Extreme Pressure Additive of Surface Coated LaF3 Nanoparticles in Liquid Paraffin,” Wear, 249, pp. 333–337. [CrossRef]
Deng, W., Ji, X., Chen, Q., and Banks, C. E., 2011, “Electrochemical Capacitors Utilizing Transition Metal Oxides: An Update of Recent Developments,” RSC Adv., 1, pp. 1171–1178. [CrossRef]
Svenskaya, Y., Parakhonskiy, B., Haase, A., Atkin, V., Lukyanets, E., Gorin, D., and Antolini, R., 2013, “Anticancer Drug Delivery System Based on Calcium Carbonate Particles Loaded With a Photosensitizer,” Biophys. Chem., 182, pp. 11–15. [CrossRef] [PubMed]
Xu, Z., and Sun, J., 2018, “Anti-wear Mechanism Analysis of Nano-CaCO3 Additives,” 2018 4th International Conference on Energy Materials and Environment Engineering (ICEMEE 2018), Kuala Lumpur, Malaysia, E3S Web of Conferences.
Declet, A., Reyes, E., and Suárez, O., 2016, “Calcium Carbonate Precipitation: A Review of the Carbonate Crystallization Process and Applications in Bioinspired Composites,” Rev. Adv. Mater. Sci., 44, pp. 87–107.
Mohammadifard, H., and Amiri, M. C., 2018, “On Tailored Synthesis of Nano CaCO3 Particles in a Colloidal Gas Aphron System and Evaluating Their Performance With Response Surface Methodology for Heavy Metals Removal From Aqueous Solutions,” J. Water Environ. Nanotechnol., 3, pp. 141–149.
Pérez-Villarejo, L., Takabait, F., Mahtout, L., Carrasco-Hurtado, B., Eliche-Quesada, D., and Sánchez-Soto, P. J., 2018, “Synthesis of Vaterite CaCO3 as Submicron and Nanosized Particles Using Inorganic Precursors and Sucrose in Aqueous Medium,” Ceram. Int., 44, pp. 5291–5296. [CrossRef]
Zhao, T., Zhang, F., Zhang, J., Sha, F., Xu, Q., Guo, B., and Wei, X., 2016, “Facile Preparation of Micro and Nano-Sized CaCO3 Particles by a New CO2-Storage Material,” Powder Technol., 301, pp. 463–471. [CrossRef]
Kim, B.-J., Park, E.-H., Choi, K., and Kang, K.-S., 2017, “Synthesis of CaCO3 Using CO2 at Room Temperature and Ambient Pressure,” Mater. Lett., 190, pp. 45–47. [CrossRef]
Montes-Hernández, G., Renard, F., Geoffroy, N., Charlet, L., and Pironon, J., 2007, “Calcite Precipitation from CO2–H2O–Ca(OH)2 Slurry Under High Pressure of CO2,” J. Crystal Growth, 308, pp. 228–236. [CrossRef]
Zainal, N., Zulkifli, N., Yusoff, M., Masjuki, H., and Yunus, R., 2015, “The Feasibility Study of CaCO3 Derived From Cockleshell as Nanoparticle in Chemically Modified Lubricant,” Proceedings of Malaysian International Tribology Conference, Penang, Malaysia, Nov. 16–17.
Xu, N., Zhang, M., Li, W., Zhao, G., Wang, X., and Liu, W., 2013, “Study on the Selectivity of Calcium Carbonate Nanoparticles Under the Boundary Lubrication Condition,” Wear, 307, pp. 35–43. [CrossRef]
Ji, X., Chen, Y., Zhao, G., Wang, X., and Liu, W., 2011, “Tribological Properties of CaCO3 Nanoparticles as an Additive in Lithium Grease,” Tribol. Lett., 41, pp. 113–119. [CrossRef]
Caixiang, G., Qingzhu, L., Zhuoming, G., and Guangyao, Z., 2008, “Study on Application of CeO2 and CaCO3 Nanoparticles in Lubricating Oils,” J. Rare Earths, 26, pp. 163–167. [CrossRef]
Hadiko, G., Han, Y. S., Fuji, M., and Takahashi, M., 2005, “Synthesis of Hollow Calcium Carbonate Particles by the Bubble Templating Method,” Mater. Lett., 59, pp. 2519–2522. [CrossRef]
Chen, Y., Ji, X., Zhao, G., and Wang, X., 2010, “Facile Preparation of Cubic Calcium Carbonate Nanoparticles With Hydrophobic Properties via a Carbonation Route,” Powder Technol., 200, pp. 144–148. [CrossRef]
Xu, S., Ye, Z., and Wu, P., 2015, “Biomimetic Controlling of CaCO3 and BaCO3 Superstructures by Zwitterionic Polymer,” ACS Sust. Chem. Eng., 3, pp. 1810–1818. [CrossRef]
Liu, Y., Cui, Y., and Guo, R., 2012, “Amphiphilic Phosphoprotein-Controlled Formation of Amorphous Calcium Carbonate With Hierarchical Superstructure,” Langmuir, 28, pp. 6097–6105. [CrossRef] [PubMed]
López-Arce, P., Gómez-Villalba, L., Martínez-Ramírez, S., de Buergo, MÁ, and Fort, R., 2011, “Influence of Relative Humidity on the Carbonation of Calcium Hydroxide Nanoparticles and the Formation of Calcium Carbonate Polymorphs,” Powder Technol., 205, pp. 263–269. [CrossRef]
Akhtar, K., Gul, M., Haq, I. U., Khan, R. A., Khan, Z. U., and Hussain, A., 2016, “Synthesis and Characterization of Uniform Fine Particles of Pure and Chromium-Substituted Manganese Ferrite With Low Dielectric Losses,” Ceram. Int., 42, pp. 18064–18073. [CrossRef]
Nurbas, M., Kabasakal, O. S., Asadov, Z. H., Aka-Zade, A. D., Ahmadova, G. A., and Zenouzi, M. B., 2005, “Surfactants Based on Higher Carboxylic Acids and Epoxy Compounds,” Iran. Polym. J., 14, pp. 317–322.
Barhoum, A., Rahier, H., Abou-Zaied, R. E., Rehan, M., Dufour, T., Hill, G., and Dufresne, A., 2014, “Effect of Cationic and Anionic Surfactants on the Application of Calcium Carbonate Nanoparticles in Paper Coating,” ACS Appl. Mater. Interfaces, 6, pp. 2734–2744. [CrossRef] [PubMed]
Frost, R. L., Locos, O. B., Ruan, H., and Kloprogge, J. T., 2001, “Near-Infrared and Mid-Infrared Spectroscopic Study of Sepiolites and Palygorskites,” Vib. Spectrosc., 27, pp. 1–13. [CrossRef]
Lv, J., Feng, J., Zhang, W., Shi, R., Liu, Y., Wang, Z., and Zhao, M., 2013, “Identification of Carbonates as Additives in Pressure-Sensitive Adhesive Tape Substrate With Fourier Transform Infrared Spectroscopy (FTIR) and Its Application in Three Explosive Cases,” J. Forensic Sci., 58, pp. 134–137. [CrossRef] [PubMed]
Liu, D., Zhang, M., Zhao, G., and Wang, X., 2012, “Tribological Behavior of Amorphous and Crystalline Overbased Calcium Sulfonate as Additives in Lithium Complex Grease,” Tribol. Lett., 45, pp. 265–273. [CrossRef]
Andersen, F. A., and Brecevic, L., 1991, “Infrared Spectra of Amorphous and Crystalline Calcium Carbonate,” Acta Chem. Scand., 45, pp. 1018–1024. [CrossRef]
Babou-Kammoe, R., Hamoudi, S., Larachi, F., and Belkacemi, K., 2012, “Synthesis of CaCO3 Nanoparticles by Controlled Precipitation of Saturated Carbonate and Calcium Nitrate Aqueous Solutions,” Can. J. Chem. Eng., 90, pp. 26–33. [CrossRef]
Elmay, Y., Jeguirim, M., Trouvé, G., and Said, R., 2016, “Kinetic Analysis of Thermal Decomposition of Date Palm Residues Using Coats–Redfern Method,” Energy Sour. A Recovery Util. Environ. Effects, 38, pp. 1117–1124. [CrossRef]
Zhao, G., Zhao, Q., Li, W., Wang, X., and Liu, W., 2014, “Tribological Properties of Nano-Calcium Borate as Lithium Grease Additive,” Lubrication Sci., 26, pp. 43–53. [CrossRef]
ASTM G99–95a, 2000, Standard Test Method for Wear Testing With a Pin-on-Disk Apparatus, ASTM International, West Conshohocken, PA, pp. 1–6.
Zhang, M., Wang, X., Fu, X., and Xia, Y., 2009, “Performance and Anti-Wear Mechanism of CaCO3 Nanoparticles as a Green Additive in Poly-alpha-Olefin,” Tribol. Int., 42, pp. 1029–1039. [CrossRef]
Jin, D., and Yue, L., 2008, “Tribological Properties Study of Spherical Calcium Carbonate Composite as Lubricant Additive,” Mater. Lett., 62, pp. 1565–1568. [CrossRef]
Gay, P.-A., Bercot, P., and Pagetti, J., 2001, “Electrodeposition and Characterisation of Ag–ZrO2 Electroplated Coatings,” Surf. Coatings Technol., 140, pp. 147–154. [CrossRef]
Battez, A. H., Gonzalez, R., Felgueroso, D., Fernández, J., del Rocío Fernández, M., García, M., and Penuelas, I., 2007, “Wear Prevention Behaviour of Nanoparticle Suspension Under Extreme Pressure Conditions,” Wear, 263, pp. 1568–1574. [CrossRef]
Sunqing, Q., Junxiu, D., and Guoxu, C., 1999, “Tribological Properties of CeF3 Nanoparticles as Additives In Lubricating Oils,” Wear, 230, pp. 35–38. [CrossRef]
Battez, A. H., Viesca, J., González, R., Blanco, D., Asedegbega, E., and Osorio, A., 2010, “Friction Reduction Properties of a CuO Nanolubricant Used as Lubricant for a NiCrBSi Coating,” Wear, 268, pp. 325–328. [CrossRef]
Kbulut, M., 2012, “Nanoparticle-Based Lubrication Systems,” J. Powder Metallur. Min., 1, e101.
Battez, A. H., González, R., Viesca, J., Fernández, J., Fernández, J. D., Machado, A., Chou, R., and Riba, J., 2008, “CuO, ZrO2 and ZnO Nanoparticles as Antiwear Additive in Oil Lubricants,” Wear, 265, pp. 422–428. [CrossRef]
Wu, Y., Tsui, W., and Liu, T., 2007, “Experimental Analysis of Tribological Properties of Lubricating Oils With Nanoparticle Additives,” Wear, 262, pp. 819–825. [CrossRef]

Figures

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Fig. 2

Low- and high-magnification SEM images of calcium carbonate particles obtained by bubbling carbon dioxide gas with a flow rate of 0.5 mol/l for 70 s through a 1.95 × 10−2 mol/l solution of calcium hydroxide maintained at 30 °C

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Fig. 3

Schematics of the experimental setup for the synthesis of calcium carbonate powder by the bubbling of carbon dioxide gas through a calcium hydroxide solution

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Fig. 7

Decomposition fraction “α” against temperature for the particles of calcium carbonate

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Fig. 8

Plot of ln[−ln(1−α)/T2] against 1/T for the particles of calcium carbonate shown in Fig. 2

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Fig. 9

Wear track width of steel stubs lubricated by CLG containing 5 wt. % of (a) CCC, (b) commercial CaCO3, and (c) additive-free CLG

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Fig. 1

Selected SEMs of the particles obtained during optimization of the recipe for uniform fine particles of calcium carbonate, by the reaction of either carbonated water or CO2 and Ca(OH)2 solution under different experimental conditions

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Fig. 4

XRD of the cubic calcium carbonate particles shown in Fig. 2

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Fig. 5

Fourier transform infrared spectra of the calcium carbonate particles shown in Fig. 2

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Fig. 6

Thermogravimetric (a) and differential thermal analysis (b) curves of the cubic calcium carbonate particles shown in Fig. 2

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Fig. 10

Coefficient of friction versus time for (A) blank, (B) 5 wt. % commercial CaCO3 additized, and (C) 5 wt. % CCC-additized CLG

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Fig. 11

Wear volume of (A) an additive-free CLG and varying amounts of (B) commercial CaCO3, and (C) CCC particles in CLG

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Fig. 12

Friction coefficient of (A) additive-free CLG and varying amounts of (B) commercial CaCO3, and (C) CCC particles in CLG

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Fig. 13

SEM images at different magnifications of commercial CaCO3 obtained from BDH Chemicals Limited (UK)

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Fig. 14

EDX spectrum of the worn surface of a steel stub lubricated by CLG containing 5 wt. % of CCC particles

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