The mixed sodium manganese ferrite thermochemical cycle for sustainable hydrogen production is reviewed. Both the hydrogen production step and the reaction that leads to the regeneration of initial reactants are described as multistep reactions. The chemical cyclability of the reactive system has been demonstrated at .
1.
Tamaura
, Y.
, Ueda
, Y.
, Matsunami
, J.
, Hasegawa
, N.
, Nezuka
, M.
, Sano
, T.
, and Tsuji
, M.
, 1999, “Solar Hydrogen Production by Using Ferrites
,” Sol. Energy
0038-092X, 65
, pp. 55
–57
.2.
Kodama
, T.
, and Gokon
, N.
, 2007, “Thermochemical Cycles for High-Temperature Solar Hydrogen Production
,” Chem. Rev.
0009-2665, 107
, pp. 4048
–4077
.3.
Funk
, J. E.
, 2001, “Thermochemical Hydrogen Production: Past and Present
,” Int. J. Hydrogen Energy
0360-3199, 26
, pp. 185
–190
.4.
Steinfeld
, A.
, 2005, “Solar Thermochemical Production of Hydrogen—A Review
,” Sol. Energy
0038-092X, 78
, pp. 603
–615
.5.
Agrafiotis
, C.
, Roeb
, M.
, Kostandopoulos
, A. G.
, Nalbandian
, L.
, Zaspalis
, V. T.
, Sattler
, C.
, Stobbe
, P.
, and Steele
, A. M.
, 2005, “Solar Water Splitting for Hydrogen Production With Monolithic Reactors
,” Sol. Energy
0038-092X, 79
, pp. 409
–421
.6.
Kaneko
, H.
, Ochiai
, Y.
, Shimizu
, K.
, Hosokawa
, Y.
, Gokon
, N.
, and Tamaura
, Y.
, 2002, “Thermodynamic Study Based on the Phase Diagram of the Na2O–MnO–Fe2O3 System for H2 Production in Three-Step Water Splitting With Na2CO3/MnFe2O4/Fe2O3
,” Sol. Energy
0038-092X, 72
, pp. 377
–383
.7.
Seralessandri
, L.
, Varsano
, F.
, La Barbera
, A.
, and Padella
, F.
, 2006, “On the Oxygen Releasing Step in the Water-Splitting Thermochemical Cycle by MnFe2O4–Na2CO3 System
,” Scr. Mater.
1359-6462, 55
, pp. 875
–877
.8.
Seralessandri
, L.
, Bellusci
, M.
, Alvani
, C.
, La Barbera
, A.
, Padella
, F.
, and Varsano
, F.
, 2008, “Chemical Equilibria Involved in the Oxygen-Releasing Step of Manganese Ferrite Water Splitting Thermochemical Cycle
,” J. Solid State Chem.
0022-4596, 181
, pp. 1992
–1997
.9.
Ewan
, B. C. R.
, and Allen
, R. W. K.
, 2006, “Limiting Thermodynamic Efficiencies of Thermochemical Cycles Used for Hydrogen Generation
,” Green Chem.
1463-9262, 8
, pp. 988
–994
.10.
Larson
A. C.
, and Von Dreele
R. B.
, 2004, “General Structure Analysis System (GSAS)
,” Los Alamos National Laboratory Report No. LAUR 86-748.11.
Alvani
, C.
, Ennas
, G.
, La Barbera
, A.
, Marongiu
, G.
, Padella
, F.
, and Varsano
, F.
, 2005, “Synthesis and Characterization of Nanocrystalline MnFe2O4: Advances in Thermochemical Water Splitting
,” Int. J. Hydrogen Energy
0360-3199, 30
, pp. 1407
–1411
.12.
Padella
, F.
, Alvani
, C.
, La Barbera
, A.
, Ennas
, G.
, Liberatore
, R.
, and Varsano
, F.
, 2005, “Mechanosynthesis and Process Characterization of Nanostructured Manganese Ferrite
,” Mater. Chem. Phys.
0254-0584, 90
, pp. 172
–177
.13.
Alvani
, C.
, La Barbera
, A.
, Ennas
, G.
, Padella
, F.
, and Varsano
, F.
, 2006, “Hydrogen Production by Using Manganese Ferrite: Evidences and Benefits of a Multi-Step Reaction Mechanism
,” Int. J. Hydrogen Energy
0360-3199, 31
, pp. 2217
–2222
.14.
Roine
A.
, HSC Chemistry 5.11. Outokumpu Research Oy, Pori, Finland.15.
Ozawa
, T. C.
, and Kang
, S. J.
, 2004, “Balls & Sticks: Easy-to-Use Structure Visualization and Animation Creating Program
,” J. Appl. Crystallogr.
0021-8898, 37
, p. 679
.16.
Mendiboure
, A.
, Delmas
, C.
, and Hagenmuller
, P.
, 1985, “Electrochemical Intercalation and Deintercalation of NaxMnO2 Bronzes
,” J. Solid State Chem.
0022-4596, 57
, pp. 323
–331
.17.
Delmas
, C.
, Fouassier
, C.
, and Hagenmuller
, P.
, 1980, “Structural Classification and Properties of the Layered Oxides
,” Physica B
0921-4526, 99
, pp. 81
–85
.18.
Takeda
, Y.
, Nakahara
, K.
, Nishijima
, M.
, Imanishi
, N.
, Yamamoto
, O.
, Takano
, M.
, and Kanno
, R.
, 1994, “Sodium Deintercalation From Sodium Iron Oxide
,” Mater. Res. Bull.
0025-5408, 29
, pp. 659
–666
.19.
Seralessandri
, L.
, Bellusci
, M.
, Padella
, F.
, Santini
, A.
, and Varsano
, F.
, 2008, “The Oxygen-Releasing Step in the Water Splitting Cycle by MnFe2O4–Na2CO3 System
,” Int. J. Hydrogen Energy
0360-3199, 34
, pp. 4546
–4550
.Copyright © 2010
by American Society of Mechanical Engineers
You do not currently have access to this content.